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However, we consider only molecules in different energy states as distinguishable. That is, the N-L molecules in the e1 box are taken to be indistinguishable, as are the N2 molecules in the e 2 box, and so on. We must then divide out the permutations that should not be present. Thus in the case of system 2, there are 6! ways of permuting the molecules in the € Xbox, 3 ! ways for the e 2 box, and 1 ! or one way for the e 3 box. ) = 840. The general statements of the preceding conditions are then Ν =YjNi = constant, Ε = £ Ni€i = constant, W = — = (2-8) (2-9) (2-10) where N{ denotes the number of molecules in the ith state of energy e, and W is the statistical weight or probability of the particular distribution.

Condensation pressure for the liquid state. It is actually possible to compress vapors beyond the condensation pressure; the system is unstable toward conden­ sation, but if the vapor is free of dust, the first appearance of liquid droplets may be delayed. The effect is known as supersaturation and occurs because a small liquid drop has a higher vapor pressure than does the bulk liquid, by virtue of having a large surface-to-volume ratio and consequently an appreciable added energy due to the surface energy.

Soc. 5 8 , 2585. WESTON, F. (1950). "An Introduction to Thermodynamics. " Addison-Wesley, Reading, Massachusetts. EXERCISES AND PROBLEMS As noted in the Preface, each section of this type is divided into three parts. The first consists of Exercises, or very straightforward illustrations of the textual material. The Problems section contains more demanding and often longer applications of the same material; and, as the name indicates, Special Topics Problems draw on the Special Topics section of the chapter.

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